Ok it won't let me upload an attatchment so its in my Radian photo album on my profile. Look at the harness and see how much room there is in it.
I just looked at the picture and I know based on the length of the safestop and the harness slots that your dd is using that the harness should tighten further.
My suggestion for the time being would be to loosen the install of the seat, tighten your dd's harness, and then re-tighten the installation. My guess is that the safestop is either getting compressed between the vehicle seat and the back of the shell, or perhaps it's not able to slide around the bend at the bottom of the seat. Of course, with 2 kids sharing the seat, tightening the harness before installation isn't really practical - but it would be a solution if she was the only one using the seat.
It would be a royal pain in the butt to not be able to loosen and tighten every time if that's what you're used to, but physically the harness can most definitely be tightened enough.
We drive an Outlook which is the cousin to your Acadia and has the same interior seats. Do you have any seats installed in the outboard positions, and does anyone else ride back there? You don't have to have the seat reclined if it's only a seat in the center position, but if nobody else rides in the 2nd row, I would try reclining the seatback and see if that removes the interference. (If you have a seat installed in the outboard position using the lower anchors, then you have to have the seatbacks reclined and both sides of the seat must be reclined to match.) If you have adult passengers who ride back there, then I'd leave it upright just because you don't want the adult passengers as reclined as how they'd end up with the bench reclined.
Knowing how the radian installs in that position with the seat reclined, I can imagine that if you have the seat upright right now, the shell is pressed very firmly along most of it's length in to the back of the vehicle seat and it's probably a case of it not being able to slide freely.
If you don't currently have the seat reclined and decide to give it a try, there is the very slight chance that once you recline it you may be able to pull the harness enough to the side from the back of the shell that you may be able to take the safestop on and off without having to uninstall the seat. That may actually fix both your problems if you don't have the seat reclined already, but if you do decide to go that route, just be careful to keep track of the harness straps so you don't end up with any twists.